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| 37294874 | Tuning the Type 1 Reduction Potential of Multicopper Oxidases: Uncoupling the Effects of Electrostatics and H-Bonding to Histidine Ligands. | J Am Chem Soc | 2023 |
| 37590931 | X-ray Spectroscopic Study of the Electronic Structure of a Trigonal High-Spin Fe(IV)â¿O Complex Modeling Non-Heme Enzyme Intermediates and Their Reactivity. | J Am Chem Soc | 2023 |
| 37871225 | Heterologous synthesis of the complex homometallic cores of nitrogenase P- and M-clusters in <i>Escherichia coli</i>. | Proc Natl Acad Sci U S A | 2023 |
| 37441786 | Kβ X-ray Emission Spectroscopy of Cu(I)-Lytic Polysaccharide Monooxygenase: Direct Observation of the Frontier Molecular Orbital for H<sub>2</sub>O<sub>2</sub> Activation. | J Am Chem Soc | 2023 |
| 35202982 | S K-edge XAS of Cu<sup>II</sup>, Cu<sup>I</sup>, and Zn<sup>II</sup> oxidized Dithiolene complexes: Covalent contributions to structure and the Jahn-Teller effect. | J Inorg Biochem | 2022 |
| 35550498 | Radical SAM-dependent formation of a nitrogenase cofactor core on NifB. | J Inorg Biochem | 2022 |
| 35925843 | Incorporation of an Asymmetric Mo-Fe-S Cluster as an Artificial Cofactor into Nitrogenase. | Chembiochem | 2022 |
| 36219763 | Methane Activation by a Mononuclear Copper Active Site in the Zeolite Mordenite: Effect of Metal Nuclearity on Reactivity. | J Am Chem Soc | 2022 |
| 35218104 | Characterization of a Nitrogenase Iron Protein Substituted with a Synthetic [Fe<sub>4</sub> Se<sub>4</sub> ] Cluster. | Angew Chem Int Ed Engl | 2022 |
| 34635813 | Tracing the incorporation of the "ninth sulfur" into the nitrogenase cofactor precursor with selenite and tellurite. | Nat Chem | 2021 |
| 33684290 | A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity. | J Am Chem Soc | 2021 |
| 33597529 | Short-lived metal-centered excited state initiates iron-methionine photodissociation in ferrous cytochrome c. | Nat Commun | 2021 |
| 33730507 | Effect of 3d/4p Mixing on 1s2p Resonant Inelastic X-ray Scattering: Electronic Structure of Oxo-Bridged Iron Dimers. | J Am Chem Soc | 2021 |
| 33136386 | Kβ X-ray Emission Spectroscopy as a Probe of Cu(I) Sites: Application to the Cu(I) Site in Preprocessed Galactose Oxidase. | Inorg Chem | 2020 |
| 31945647 | Biological sulfur in the blood cells of Ascidia ceratodes: XAS spectroscopy and a cellular-enzymatic hypothesis for vanadium reduction in the ascidians. | J Inorg Biochem | 2020 |
| 32094179 | Evaluation of a concerted vs. sequential oxygen activation mechanism in α-ketoglutarate-dependent nonheme ferrous enzymes. | Proc Natl Acad Sci U S A | 2020 |
| 30718404 | Resonant inelastic X-ray scattering determination of the electronic structure of oxyhemoglobin and its model complex. | Proc Natl Acad Sci U S A | 2019 |
| 31411369 | Spectroscopic Characterization of an Eight-Iron Nitrogenase Cofactor Precursor that Lacks the "9<sup>th</sup> Sulfur". | Angew Chem Int Ed Engl | 2019 |
| 31339709 | The Electronic Structure of the Metal Active Site Determines the Geometric Structure and Function of the Metalloregulator NikR. | Biochemistry | 2019 |
| 31046257 | X-ray Absorption Spectroscopy as a Probe of Ligand Noninnocence in Metallocorroles: The Case of Copper Corroles. | Inorg Chem | 2019 |
| 30860832 | Tuning the Geometric and Electronic Structure of Synthetic High-Valent Heme Iron(IV)-Oxo Models in the Presence of a Lewis Acid and Various Axial Ligands. | J Am Chem Soc | 2019 |
| 30824597 | Formylglycine-generating enzyme binds substrate directly at a mononuclear Cu(I) center to initiate O<sub>2</sub> activation. | Proc Natl Acad Sci U S A | 2019 |
| 30876351 | Synchrotron X-radiolysis of l-cysteine at the sulfur K-edge: Sulfurous products, experimental surprises, and dioxygen as an oxidoreductant. | J Chem Phys | 2019 |
| 29610304 | Structural characterization of a non-heme iron active site in zeolites that hydroxylates methane. | Proc Natl Acad Sci U S A | 2018 |
| 30210769 | A mononuclear nonheme {FeNO}<sup>6</sup> complex: synthesis and structural and spectroscopic characterization. | Chem Sci | 2018 |
| 30429333 | Mechanism of selective benzene hydroxylation catalyzed by iron-containing zeolites. | Proc Natl Acad Sci U S A | 2018 |
| 29701293 | Oxidation of Naphthalene with a Manganese(IV) Bis(hydroxo) Complex in the Presence of Acid. | Angew Chem Int Ed Engl | 2018 |
| 28068071 | Spin-Polarization-Induced Preedge Transitions in the Sulfur K-Edge XAS Spectra of Open-Shell Transition-Metal Sulfates: Spectroscopic Validation of Ï¿-Bond Electron Transfer. | Inorg Chem | 2017 |
| 29091732 | A Six-Coordinate Peroxynitrite Low-Spin Iron(III) Porphyrinate Complex-The Product of the Reaction of Nitrogen Monoxide (·NO<sub>(g)</sub>) with a Ferric-Superoxide Species. | J Am Chem Soc | 2017 |
| 28970624 | K- and L-edge X-ray Absorption Spectroscopy (XAS) and Resonant Inelastic X-ray Scattering (RIXS) Determination of Differential Orbital Covalency (DOC) of Transition Metal Sites. | Coord Chem Rev | 2017 |
| 28642436 | Metalloprotein entatic control of ligand-metal bonds quantified by ultrafast x-ray spectroscopy. | Science | 2017 |
| 28715891 | Sulfur K-Edge XAS Studies of the Effect of DNA Binding on the [Fe<sub>4</sub>S<sub>4</sub>] Site in EndoIII and MutY. | J Am Chem Soc | 2017 |
| 28006897 | L-Edge X-ray Absorption Spectroscopic Investigation of {FeNO}<sup>6</sup>: Delocalization vs Antiferromagnetic Coupling. | J Am Chem Soc | 2017 |
| 26930130 | Spectroscopic and Theoretical Study of Cu(I) Binding to His111 in the Human Prion Protein Fragment 106-115. | Inorg Chem | 2016 |
| 27626829 | Structure of the Reduced Copper Active Site in Preprocessed Galactose Oxidase: Ligand Tuning for One-Electron O<sub>2</sub> Activation in Cofactor Biogenesis. | J Am Chem Soc | 2016 |
| 27506795 | Assembly scaffold NifEN: A structural and functional homolog of the nitrogenase catalytic component. | Proc Natl Acad Sci U S A | 2016 |
| 27475372 | Solvation structure of the halides from x-ray absorption spectroscopy. | J Chem Phys | 2016 |
| 25725734 | A high-resolution XAS study of aqueous Cu(II) in liquid and frozen solutions: pyramidal, polymorphic, and non-centrosymmetric. | J Chem Phys | 2015 |
| 26515097 | Uncoupling binding of substrate CO from turnover by vanadium nitrogenase. | Proc Natl Acad Sci U S A | 2015 |
| 24328215 | Biosynthesis of nitrogenase metalloclusters. | Chem Rev | 2014 |
| 25475739 | Resonant inelastic X-ray scattering on ferrous and ferric bis-imidazole porphyrin and cytochrome c: nature and role of the axial methionine-Fe bond. | J Am Chem Soc | 2014 |
| 25362050 | Goniometer-based femtosecond crystallography with X-ray free electron lasers. | Proc Natl Acad Sci U S A | 2014 |
| 24841533 | A zinc linchpin motif in the MUTYH glycosylase interdomain connector is required for efficient repair of DNA damage. | J Am Chem Soc | 2014 |
| 24821432 | Hydroxo-bridged dicopper(II,III) and -(III,III) complexes: models for putative intermediates in oxidation catalysis. | J Am Chem Soc | 2014 |
| 24889637 | Spectroscopic and computational insight into the activation of O2 by the mononuclear Cu center in polysaccharide monooxygenases. | Proc Natl Acad Sci U S A | 2014 |
| 24884723 | Sulfur K-edge X-ray absorption spectroscopy and density functional theory calculations on monooxo Mo(IV) and bisoxo Mo(VI) bis-dithiolenes: insights into the mechanism of oxo transfer in sulfite oxidase and its relation to the mechanism of DMSO reductase. | J Am Chem Soc | 2014 |
| 24333825 | XAS spectroscopy, sulfur, and the brew within blood cells from Ascidia ceratodes. | J Inorg Biochem | 2014 |
| 23259487 | Iron L-edge X-ray absorption spectroscopy of oxy-picket fence porphyrin: experimental insight into Fe-O2 bonding. | J Am Chem Soc | 2013 |
| 24131028 | Metal-ligand covalency of iron complexes from high-resolution resonant inelastic X-ray scattering. | J Am Chem Soc | 2013 |
| 24102191 | L-edge X-ray absorption spectroscopy and DFT calculations on Cu2O2 species: direct electrophilic aromatic attack by side-on peroxo bridged dicopper(II) complexes. | J Am Chem Soc | 2013 |